The Fluorination of Carbon Monoxide, Carbonyl Chloride, and Carbonyl Fluoride
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چکیده
منابع مشابه
Satellite Observations of Stratospheric Carbonyl Fluoride
The vast majority of emissions of fluorinecontaining molecules are anthropogenic in nature, e.g. chlorofluorocarbons (CFCs), hydrochlorofluorocarbons (HCFCs), and hydrofluorocarbons (HFCs). These molecules slowly degrade in the atmosphere, leading to the formation of HF, COF2, and COClF, which are the main fluorinecontaining species in the stratosphere. Ultimately both COF2 and COClF further de...
متن کاملOn the heat of formation of carbonyl fluoride, CF2O
In light of the recent controversy surrounding its heat of formation, CF2O was reexamined by photoionization mass spectrometry. In particular, the CO fragment ion yield curve from CF2O was interpreted in terms of a retarded CO1F2 process, and a more facile two-step fragmentation to CO12F. The former process produces a weak, slowly growing tail region without a clear onset, while the latter occu...
متن کاملCarbonyl(diphenylcyclopentadienyl)- und Carbonyl(tetraphenylcyclopentadienyl)rhodium(I) Komplexe Carbonyl(diphenylcyclopentadienyl)- and Carbonyl(tetraphenylcyclopentadienyl)rhodium(I) Complexes
[Rh(CO)2Cl] 2 reacts with 1,3-diphenylcyclopentadienyl sodium or tetraphenylcyclopentadienyl sodium with formation of (l,3-P h2C5H3)Rh(CO ) 2 (1) or (C5HPh4)Rh(CO )2 (2), respectively. The reaction of 1 or 2 with PPh3 yields the corresponding carbonyl(cyclopentadienyl)(triphenylphosphane)rhodium complexes (l,3 -P h 2C5H3)Rh(CO)(PPh3) (3) or (C5HPh4)Rh(CO)(PPh3) (4). The 'H and ' C reported and ...
متن کاملThe flux of carbonyl sulfide and carbon disulfide
The flux of carbonyl sulfide and carbon disulfide between the atmosphere and a spruce forest X. Xu, H. G. Bingemer, and U. Schmidt Institute for Meteorology and Geophysics, University of Frankfurt, P.O. Box 111932, 60054 Frankfurt am Main, Germany now at Max Planck Institute for Chemistry, Mainz, Germany Received: 9 January 2002 – Accepted: 19 February 2002 – Published: 21 February 2002 Corresp...
متن کاملFormation of carbonyl chloride in carbon tetrachloride metabolism by rat liver in vitro.
In order to identify intermediates of CCl4 metabolism, whole, suitably fortified rat liver homogenates were incubated with 14CCl4 in the presence and absence of "pools" of unlabeled suspected intermediates. In the presence of NADH or NADPH, incorporation of radioactivity was rapid and substantial in CO2, lipid, protein, and the acid-soluble fraction. It was not influenced by the presence of lar...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1970
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.43.2980